For all those guys who are beginers in powershell , here is a cool tip:
Fist get the mail box thru Get-mailbox command
$mailbox = get-mailbox vikas
Second get in to multivalued attribute & add one more value
$mailbox.emailaddresses+=”abc@xyz.com”,a.bc@xyz.com”
Third set the value using pipe & set mailbox
$mailbox | set-mailbox